The team at Thingspeak have been experimenting with the Freetronics Eleven and Ethernet shield, and also published a great tutorial that interfaces an IObridge web gateway module with our gear to create a device that parses Google weather and tells the user if the weather is bad enough to wear a jacket. The Arduino sketch is very simple due to the thingspeak API, and it is available for download. A simple tutorial, however a great starting point.
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Since publishing their article, you can now save space and money by using the Freetronics EtherTen:
Apart from being fully Arduino Uno-compatible, it has onboard Ethernet, microSD socket, full USB connection (no pesky FTDI cables needed) and supports optional Power-over-Ethernet.